When Materials Break: How Heat and Randomness Shape the Fate of Cracks and Adhesion.

Two scientific papers resulting from a Franco-Italian collaboration shed new light on the fundamental phenomena of adhesion and fracture, two seemingly distinct but intimately related processes.  Both are in fact strongly influenced by the random and minute motions of atoms known as thermal fluctuations.

Why do some materials hold strong while others suddenly crack or peel apart? This seemingly simple question hides a world of complex physics, where heat and randomness often call the shots.

Two recent scientific studies shed light on this mystery, showing that thermal fluctuations — the tiny, random movements of atoms caused by heat — can play a crucial role in how and when materials fail. These works were carried out as part of Claudia Binetti’s doctoral thesis, supervised by Stefano Giordano at IEMN, and by Giuseppe Puglisi (DICATECh, Bari) and Nicola M. Pugno (Dicam, Trento) on the Italian side.

In the first study, the focus is on adhesion — the subtle force that keeps surfaces stuck together. Think of how a gecko walks on the ceiling, or why a sticky note stays in place. The researchers built a mathematical model that links the microscopic forces between molecules to the larger-scale behavior of materials. Surprisingly, they found that even small temperature changes can cause a sudden loss of adhesion, just like how glue sometimes fails when it gets too warm.

The second study dives into fracture — how cracks start and spread. Conventional wisdom says that materials break when the stress becomes too great. But this work shows that cracks can nucleate much earlier, triggered by seemingly harmless thermal vibrations. Once started, a crack can grow in unexpected ways, driven by random fluctuations that are usually ignored

What ties these two studies together is a multiscale approach — a theoretical framework that connects the unpredictable world of atoms to the visible properties of real-world materials. In both cases, the researchers observed phase transitions: abrupt shifts from one state to another (like sticking to unsticking, or unbroken to cracked), caused not just by force but by randomness amplified by temperature. These transitions help explain how materials can switch behavior suddenly, even under mild conditions.

 

This deeper understanding doesn’t just explain puzzling failures: it enables us to design more reliable and better engineered materials.

The research opens doors to exciting applications:

 In biophysics: Understanding adhesion at microscopic scales could improve how medical devices attach to tissues or how cells interact.
In materials science: Better grasping fracture mechanisms could lead to stronger, more durable materials for aerospace, electronics, or infrastructure.
In nanotechnology: Precise control of adhesion and fracture is key to designing tiny machines and sensors.
In energy and environment: Insights could help develop materials that self-heal or adapt to changing conditions.

Sometimes, making things stronger isn’t just about adding more force — it’s about listening to the subtle whispers of disorder.

Bridging borders and disciplines: this work is a shining example of international collaboration between France and Italy, merging expertise in physics, engineering, and applied mathematics. It represents a step forward in the quest to harness and control the hidden forces of nature that dictate the strength and resilience of the materials we rely on every day.

1)     Claudia Binetti, Andrea Cannizzo, Giuseppe Florio, Nicola M. Pugno, Giuseppe Puglisi, and Stefano Giordano, « Exploring the impact of thermal fluctuations on continuous models of adhesion », International Journal of Engineering Science 208 (2025) 104194, DOI: 10.1016/j.ijengsci.2024.104194.

2)     Claudia Binetti, Giuseppe Florio, Nicola M. Pugno, Stefano Giordano, and Giuseppe Puglisi, « Thermal fluctuations effects on crack nucleation and propagation », Journal of the Mechanics and Physics of Solids 201 (2025) 106157, DOI: 10.1016/j.jmps.2025.106157.

 Stefano.Giordanouniv-lille.fr